Read e-book online Advances in Inorganic Chemistry, Vol. 44 PDF

By A. G. Sykes

ISBN-10: 0120236443

ISBN-13: 9780120236442

Advances in Inorganic Chemistry provides well timed and informative summaries of the present development in quite a few topic components inside inorganic chemistry, starting from bioinorganic to reliable nation. This acclaimed serial positive aspects experiences written via specialists within the zone and is an crucial connection with complicated researchers. every one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is absolutely referenced.

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Chem. 1993,115,10344. 87. ; Wagner, F. Znorg. Chem. 1993,32,4478. 88. Herber, R. ; Felner, I. J . Chem. Phys. 1996,104,1. 89. Lichtenberger, D. ;Wright, L. ; Gruhn, N. ; Rempe, M. E. J . Organometal. Chem. 1994,478,213. ORGANOMETALLIC COMPLEXES OF FULLERENES 43 90. L6pez, J. ;Lealli, C. J. Organometal. Chem. 1994,478,161. 91. ;Fowler, P. ; Zanasi, R. Chem. Phys. Letts. 1991,184,182. 92. David, W. I. ; Ibberson, R. ; Matthewman, J. J. ; Hare, J. ; Kroto, H. ; Walton, D. R. M. Nature 1991,353,147.

Olmstead, M. M. Znorg. Chem. 1994,33,5238. 34. Park, J. ;Song, H. J . Chem. Chem. Commun. 1995,15. 35. Mavunkal, I. -H. Organometal. 1995,14,4454. 36. Balch, A. ; Costa, D. ; Noll, B. ; Olmstead, M. M. J . Am. Chem. 1995, 11 7,8926. 37. Brady, F. ;Cardin, D. ; Domin, M. J. Organometal. Chem. 1905,491,169. 38. Balch, A. ; Olmstead, M. M. Ang. Chem. Int. Ed. 1996,35, 188. 39. Balch, A. ; Costa, D. ; NOH,B. ; Olmstead, M. M. Inorg. Chem. 1996,35,458. 40. ; Itoh, K. J . Chem. Chem. Commun. 1992,377.

For both n = 1 and 2, there is disorder with the 0 occurring in as many as seven different sites. The major forms are shown next and involve the Ir and 0 centers coordinating to adjacent double bonds. No doubt the oxophilic Ir center is initially attracted to a double bond adjacent to the epoxide 0 atom. 4 . Internal Structure of the Fullerene As far as the fullerene internal structure is concerned, there is little change on metal complexation. The metal bound transannular [6,61 bond is elongated relative to the remaining fullerene C=C bonds.

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Advances in Inorganic Chemistry, Vol. 44 by A. G. Sykes

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